Sperlingite

(H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)] [(H2O)9(OH)]·4H2O
IMA status
  • Approved
IMA symbol
Sper
Also known as
  • Sperlingiet

Where it forms, where it's found

Geological setting

in corrosion pits of altered zwieselite

Type locality
Hagendorf South Pegmatite
  1. Hagendorf
  2. Waidhaus
  3. Neustadt an der Waldnaab District
  4. Upper Palatinate
  5. Bavaria
  6. Germany

49.6503°, 12.4597°

1recorded occurrences
Source · OpenStreetMap

Physical

Colour
colourless
Density
2.40 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 82.7°
Refractive index
1.6 – 1.635
Surface relief
Moderate
Principal indices
nα 1.600 · nβ 1.615 · nγ 1.635
Pleochroism
Non-pleochroic
Dispersion
none
Notes

α = 1.600(est)

Michel-Lévy diagramhighlighted lineδ = 0.0350
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]350 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation350 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 10.428(2) Å · b = 20.281(4) Å · c = 12.223(2) Å
Cell angles
β = 90.10(3) °
Ratio a:b:c
1 : 1.945 : 1.172
Z
4
Twinning

Around the c axis

Type-locality form

prisms with pyramidal terminations, which are predominantly only 5 to 20 μm in size, rarely to 60 μm and frequently are multiply intergrown and are overgrown with smaller crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3315.999527.967
56.54%
15PPhosphorusPhosphorus430.974123.896
13.27%
26FeIronIron155.84555.845
5.98%
25MnManganeseManganese154.93854.938
5.88%
13AlAluminiumAluminium226.98253.964
5.78%
22TiTitaniumTitanium147.86747.867
5.12%
19KPotassiumPotassium139.09839.098
4.19%
1HHydrogenHydrogen301.00830.240
3.24%
Total933.815100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Sperlingiet

In other languages

German
Sperlingit
Italian
sperlingite

Classification

Strunz
10th ed.

8.DH.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.35SperlingiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 2024Rewitzer, Christian, Hochleitner, Rupert, Grey, Ian E., Kampf, Anthony R., Boer, Stephanie, MacRae, Colin M., Mumme, William G., Wilson, Nicholas C., Davidson, Cameron J. (2024) Sperlingite, (H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)][(H2O)9(OH)]⋅4H2O, a new paulkerrite-group mineral, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany. Mineralogical Magazine, 88 (5). 576-584 doi:10.1180/mgm.2024.40DOI: 10.1180/mgm.2024.40
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sperlingite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sperlingite-471064},
  note      = {Accessed 2026-05-11}
}