Parasymplesite

Fe2+3(AsO4)2 · 8H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Psym
Discovered
1954
Also known as
  • Parasymplesiet

Where it forms, where it's found

Geological setting

Oxidized polymetallic veins. Contact zone of limestone with granitic diorite.

Type locality
Kiura Mine
  1. Saiki City
  2. Oita Prefecture
  3. Japan
116recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Light green to leek green · may be greenish black · also deep blue
Streak
Blue white
Tenacity
flexible
Cleavage
Perfect

(110)

Density
3.01 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 86.5°
Refractive index
1.628 – 1.705
Surface relief
High
Principal indices
nα 1.628 – 1.635 · nβ 1.660 – 1.668 · nγ 1.702 – 1.705
Birefringence
0.08
Pleochroism
Strong

Weak to strong; X = deep blue to bluish green, Y = nearly colorless to yellowish, Z = colorless to brownish yellow.

Dispersion
r>v weak to distinct
Extinction
X = b, Z ∧ c = 29.0-31.5°
UV response
Not fluorescent
Notes

Absorption: X > Y = Z (Sturmann 1976)

Michel-Lévy diagramhighlighted lineδ = 0.0800
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]800 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation800 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 10.3519(10) Å · b = 13.6009(13) Å · c = 4.7998(4) Å
Cell angles
β = 104.816(2) °
Ratio a:b:c
1 : 1.314 : 0.464
Z
4
Morphology

Type material: Thick tabular after (010), with large (010) and (201) or stout-prismatic with (110) and other prisms nearly equally well developed and with relatively large (502). Numerous prismatic faces are observed in both types of crystals, other kinds of faces being only occasionally noticed.

Translation gliding
T (110), t (001)
Type-locality form

Radiating aggregates of fine crystals. Crystals to 3 x 1.5 x 1 mm.

Comment

Cell parameters from Hongu et al. (2021).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
43.42%
26FeIronIron355.845167.535
28.42%
33AsArsenicArsenic274.922149.844
25.42%
1HHydrogenHydrogen161.00816.128
2.74%
Total589.491100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Parasymplesiet

In other languages

German
Parasymplesit
Spanish
Parasimplesita
Italian
Parasymplesite
Japanese
亜砒藍鉄鉱

Classification

Strunz
10th ed.

8.CE.40

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.40ParasymplesiteSpecies
Dana
8th ed.

40.03.06.06

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.06Vivianite GroupGroup
  • 40.03.06.06ParasymplesiteSpecies
CIM

20.9.7

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.9Arsenates of FeGroup
  • 20.9.7ParasymplesiteSpecies

Group, growth & confusion

Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1954Tei-ichi Ito, Hideo Minato, and Kin-ichi Sakurai (1954): Parasymplesite, a New Mineral Polymorphous with Symplesite. Proceedings of the Japan Academy, 30, 318-324.
  2. 1954Ito, T.-I., Minato, H., Sakurai, K.-I. (1954): Parasymplesite, a New Mineral Polymorphous with Symplesite. Proceedings of the Japan Academy, 30, 318-324.
  3. 1976Sturman, B.D. (1976) New data for köttigite and parasymplesite. The Canadian Mineralogist, 14(4), 437-441. https://rruff.info/rruff_1.0/uploads/CM14_437.pdf
  4. 1977Cesbron, Fabien; Sichère, Marie-Claude; Vachey, Hélène (1977) Propriétés cristallographiques et comportement thermique des termes de la série koettigite-parasymplésite. Bulletin de Minéralogie, 100 (6). 310-314 doi:10.3406/bulmi.1977.7154DOI: 10.3406/bulmi.1977.7154
  5. 2005(2005) Parasymplesite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Parasymplesite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/parasymplesite-3114},
  note      = {Accessed 2026-05-11}
}