Mixite

Cu6Bi(AsO4)3(OH)6 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mix
Discovered
1879
Also known as
  • Mixiet

Where it forms, where it's found

Geological setting

Secondary mineral in oxidationn zone of copper-bismuth deposits.

Type locality
Jáchymov
  1. Karlovy Vary District
  2. Karlovy Vary Region
  3. Czech Republic

50.3661°, 12.9233°

174recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Dull · brilliant
Transparency
Transparent · Translucent
Colour
pale green · blue-green · emerald-green · white · light green to colourless in transmitted light.
Streak
Pale bluish green
Density
3.79 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.743 – 1.83
Surface relief
High
Principal indices
nω 1.743 – 1.749 · nε 1.81 – 1.83
Pleochroism
Visible

O = Colourless E = Bright green

Michel-Lévy diagramhighlighted lineδ = 0.0740
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]740 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation740 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#108
Cell parameters
a = 13.646(2) Å · c = 5.92 Å
Z
2
Morphology

Crystals acicular, elongated along [0001] and deeply striated vertically. Commonly occurs matted or as radial aggregates with a partial concentric fibrous structure or cross-fiber veinlets.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper663.546381.276
32.78%
8OOxygenOxygen2115.999335.979
28.89%
33AsArsenicArsenic374.922224.766
19.32%
83BiBismuthBismuth1208.980208.980
17.97%
1HHydrogenHydrogen121.00812.096
1.04%
Total1163.097100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Mixiet

In other languages

French
Mixite
German
Mixit
Spanish
Mixita
Italian
Mixite
Chinese
砷铋铜石

Classification

Strunz
10th ed.

8.DL.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DLWith large and medium-sized cations, (OH, etc.):RO4 = 2:1Group
  • 8.DL.15MixiteSpecies
Dana
8th ed.

42.05.01.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.05(AB)7(XO4)3Zq·xH2OType
  • 42.05.01Mixite group (Arsenate Series)Group
  • 42.05.01.01MixiteSpecies
CIM

20.6.5

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.6Arsenates of BiGroup
  • 20.6.5MixiteSpecies

Group, growth & confusion

Often grow together
8 minerals

Literature, links & citation

Citations
  1. 1875Frenzel, A. (1875) Mineralogische und petrographische Mitteilungen, Vienna: 42. (as Chlorotile)
  2. 1880Schrauf, A. (1880) Ueber Arsenate von Joachimsthal. 1. Mixit, ein neues Kupferwismuthhydroarsenat. 2. Wapplerit. 3. Pharmakolith. Zeitschrift für Kristallographie, 4 (1). 277-285 doi:10.1524/zkri.1880.4.1.277DOI: 10.1524/zkri.1880.4.1.277
  3. 1888Hillebrand, W. F., Washington, H. S. (1888) Notes on certain rare copper minerals from Utah. American Journal of Science, s3-35 (208). 298-307 doi:10.2475/ajs.s3-35.208.298DOI: 10.2475/ajs.s3-35.208.298
  4. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  5. 1925Gordon, S.G. (1925) The probable identity of chlorotile with mixite. in Mineralogical Notes, 1-10. Proceedings of the Academy of Sciences, Philadelphia: 77: 1-13.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mixite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mixite-2730},
  note      = {Accessed 2026-05-11}
}