Mottramite

PbCu(VO4)(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mott
Discovered
1876
Also known as
  • Chileite
  • Cuprovanadite
  • Duftite-α
  • +4 more

History

The name points to a Cheshire village the mineral was never truly mined in. Mottramite is named for Mottram St Andrew, England, where the ore was stockpiled — though it was probably dug from the Pim Hill Mine near Shrewsbury, in neighbouring Shropshire.

The story starts a little earlier and elsewhere. In 1868 the American chemist Frederick Augustus Genth characterised a parrot-green mineral he called psittacinite. A related copper-rich material went by the name cuprodescloizite. Both, it later turned out, were the same vanadate that would be named mottramite.

That naming came in 1876. The Manchester chemist Henry Roscoe found vanadium in the green crusts coating the Cheshire ore, and the new species took the village's name. Vanadium is a hard silvery metal; here it sits locked in the crystal as a vanadate, a unit built of vanadium and oxygen. The same work gave a vanadium-bearing mica the chemist's own name — roscoelite.

Mottramite is the copper end of a chemical series that runs to descloizite, its zinc-rich twin. The type material — the reference specimens that define the species — rests at the Natural History Museum in London.

Industrial & practical applications

Mottramite has no significant industrial use today. It is essentially a collector mineral, grown in the oxidized upper zones of base-metal deposits where weathering reworks the original ores.

Its one brush with industry is over. At Tsumeb in Namibia it was once the chief vanadium-bearing mineral, but that vanadium sat only in the shallow levels of the mine. It was worked out long ago.

What demand exists now is from collectors. The mineral grows as olive-green to dark greenish-brown crusts, often branching like moss or tiny shrubs, and the best of these — many from Tsumeb — are kept as display specimens.

Where it forms, where it's found

Geological setting

Oxidation zone of vanadium bearing base metal deposits.

Type locality
Mottram St Andrew
  1. Cheshire
  2. England
  3. UK

53.3012°, -2.1906°

381recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Opaque
Colour
Grass-green · olive-green · yellow-green · siskin-green · blackish brown · nearly black

Crystals often exhibit zonal growth with varying colours.

Streak
Yellowish green
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven · Sub-Conchoidal
Density
5.9 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 73° · 2V calc = 46°
Refractive index
2.17 – 2.32
Surface relief
Very high
Principal indices
nα 2.17 · nβ 2.26 · nγ 2.32
Pleochroism
Visible

Weak to strong X=Y= canary yellow to greenish yellow Z= brownish yellow

Dispersion
strong r > v rarely r < v
Michel-Lévy diagramhighlighted lineδ = 0.1500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1500 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1500 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 7.68 Å · b = 9.27 Å · c = 6.03 Å
Ratio a:b:c
1 : 1.207 : 0.785
Z
4
Morphology

Crystals equant, dipyramidal (111), prismatic [001]. Drusy crusts of intergrown crystals common; mammillary or botryoidal surfaces.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead1207.200207.200
51.45%
8OOxygenOxygen515.99979.995
19.87%
29CuCopperCopper163.54663.546
15.78%
23VVanadiumVanadium150.94250.942
12.65%
1HHydrogenHydrogen11.0081.008
0.25%
Total402.691100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zn

Synonyms

  • Chileite
  • Cuprovanadite
  • Duftite-α
  • Psittacinite
  • Vesbin
  • Vesbina
  • α-Duftite

In other languages

French
mottramite
German
Mottramit
Spanish
Mottramita
Italian
Mottramite
Japanese
モットラム鉱
Chinese
钒铜铅矿
Simplified Chinese
钒铜铅矿
Traditional Chinese
釩銅鉛礦

Classification

Strunz
10th ed.

8.BH.40

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BHWith medium-sized and large cations, (OH,etc.):RO4 = 1:1Group
  • 8.BH.40MottramiteSpecies
Dana
8th ed.

41.05.02.02

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.05(AB)2(XO4)ZqType
  • 41.05.02Descloizite GroupGroup
  • 41.05.02.02MottramiteSpecies
CIM

21.3.10

  • 21Vanadates (and vanadates with arsenate or phosphate)Class
  • 21.3Vanadates of Al, rare earths, Pb, V or BiGroup
  • 21.3.10MottramiteSpecies

Group, growth & confusion

Often grow together
7 minerals

Literature, links & citation

Citations
  1. 1848Domeyko (1848) Annales des mines: 14: 145 (as Chileite).
  2. 1869Adam, M. (1869) Tableau minéralogique, Paris: 33 (as Cuprovanadite).
  3. 1874Genth, F. A. (1874) Contributions from the Laboratory of the University of Pennsylvania. No. III. On American Tellurium and Bismuth Minerals. Proceedings of the American Philosophical Society, 14. 223-231
  4. 1877Roscoe, H. E. (1877) IV. On two new vanadium minerals. Proceedings of the Royal Society of London, 25 (171) 109-112 doi:10.1098/rspl.1876.0023DOI: 10.1098/rspl.1876.0023
  5. 1879Scacchi (1879) Acc. Napoli, Att.: 8: 1 (as Vesbine).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mottramite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mottramite-2792},
  note      = {Accessed 2026-05-11}
}