Duftite

PbCu(AsO4)(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dft
Discovered
1920
Also known as
  • Duftiet
  • β-Duftit
  • β-Duftita

History

Most minerals are named for a place, a colour, or the chemist who first cracked their formula. Duftite is named for a mine manager. In 1920, the German mineralogist Otto Pufahl described a new lead-copper arsenate from the Tsumeb mine in what is now Namibia and named it for Gustav Bernhard Duft. Duft was a director of the company that ran the mine and had done much to encourage scientific research in the region.

Duft was no passing figure. Born in 1859 in Clausthal, Germany, he was active in Namibia from 1892 and became the second general manager of the Tsumeb mine around 1906. The mineral that carries his name came out of the same ground he oversaw — Tsumeb remains its type locality, the place where the species was first defined.

The story did not end with the naming. In 1956 the mineralogist Guillemin found that duftite was not quite one thing. He split it into two forms with slightly different internal symmetry: a calcium-free duftite-alpha, and a calcium-bearing duftite-beta. Later work folded both back under the single name duftite, but the distinction marks an early sign that the mineral's chemistry shifts from crystal to crystal.

Industrial & practical applications

Duftite has no industrial use. It forms only in the supergene zone — the weathered, oxidised cap that sits above a sulfide ore body — and never in quantities anyone could mine. Its mix of lead, copper, and arsenic would also rule it out as an ore in its own right. The only demand for it comes from mineral collectors and museums.

Even there, it is more often a supporting player than a star. It seldom forms aesthetic specimens on its own. More often it turns up as an accessory mineral, its olive to grey-green crusts giving attractive colour contrasts against brighter species. Collectors prize the Tsumeb mine in Namibia, where the same oxidation zones that defined the species also produced its best material.

One practical note follows from the chemistry rather than any use: duftite contains both lead and arsenic, so specimens are handled and stored with the care any toxic mineral deserves.

Where it forms, where it's found

Geological setting

Oxidized zone of a polymetallic deposit.

Uncommon mineral in the oxidized zone of some polymetallic sulfide deposits.

Type locality
Tsumeb Mine (Ongopolo Mine)
  1. Tsumeb
  2. Oshikoto Region
  3. Namibia

-19.2270°, 17.7276°

231recorded occurrences
Source · OpenStreetMap

Varieties

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Olive-green · grey-green

Light apple-green in transmitted light.

Streak
Pale green, white
Tenacity
brittle
Cleavage
Poor/Indistinct

Usually unobservable in botryoidal aggregates.

Fracture
Conchoidal · Sub-Conchoidal
Density
6.12 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
2.03 – 2.1
Surface relief
Very high
Principal indices
nα 2.03 – 2.04 · nβ 2.06 – 2.08 · nγ 2.08 – 2.10
Birefringence
0.055
Pleochroism
Non-pleochroic
Dispersion
r > v perceptible
Extinction
Parallel
UV response
Not Fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0550
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]550 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation550 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#44
Cell parameters
a = 7.749(1) Å · b = 9.36(1) Å · c = 5.91(1) Å
Ratio a:b:c
1 : 1.208 : 0.763
Z
4
Morphology

Usually botryoidal, rare tiny crystals elongated [001] with curved and rough faces aggregated into crusts. Pseudo-octahedral.

Comment

For P2<f>1</f>2<f>1</f>2<f>1</f>; UCD for Pnam a 7.788, b 9.223, c 6.001

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead1207.200207.200
48.56%
8OOxygenOxygen515.99979.995
18.75%
33AsArsenicArsenic174.92274.922
17.56%
29CuCopperCopper163.54663.546
14.89%
1HHydrogenHydrogen11.0081.008
0.24%
Total426.671100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Duftiet
  • β-Duftit
  • β-Duftita

In other languages

French
Duftite
German
Duftit · Duftit-alpha · Duftit-Beta
Spanish
Duftita
Italian
duftite · Duftite-alfa · Duftite-beta
Japanese
ダフト石
Chinese
砷銅鉛礦 · 砷铜铅石

Classification

Strunz
10th ed.

8.BH.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BHWith medium-sized and large cations, (OH,etc.):RO4 = 1:1Group
  • 8.BH.35DuftiteSpecies
Dana
8th ed.

41.05.01.04

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.05(AB)2(XO4)ZqType
  • 41.05.01Adelite GroupGroup
  • 41.05.01.04DuftiteSpecies
CIM

20.5.3

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.5Arsenates of Ti and PbGroup
  • 20.5.3DuftiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1920Pufahl, O. (1920) Mitteilungen über mineralien und erze von Südwestafrika, besonders solche von Tsumeb. Centralblatt für Mineralogie, Geologie und Paläontologie: 1920: 289-296.
  2. 1921Wherry, E.T., Foshag, W.F. (1921) New mineral names. American Mineralogist: 6: 140-141.
  3. 1930Barth and Berman (1930) Chemie der Erde, Jena: 5: 30.
  4. 1939Strunz, H. (1939) Mineralien der Descloizitgruppe. Konichalcit, Staszizit, Austinit, Duftit, Aräoxen, Volborthit, Pyrobelonit. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 101 (1). 496-506 doi:10.1524/zkri.1939.101.1.496DOI: 10.1524/zkri.1939.101.1.496
  5. 1940Richmond, Wallace E. (1940) Crystal chemistry of the phosphates, arsenates and vanadates of the type A2XO4(Z). American Mineralogist, 25 (7). 441-479
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Duftite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/duftite-1325},
  note      = {Accessed 2026-05-11}
}