Orthoclase

K(AlSi3O8)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Or
Discovered
1823
Also known as
  • Aglairit
  • Argillyit
  • Argillyita
  • +14 more

History

Break a fresh crystal of orthoclase and the two clean surfaces will meet at almost exactly 90°. That right angle is the mineral's name and its first claim on human attention.

The French crystallographer René Just Haüy noticed it in 1801 and called the mineral orthose, from the Greek orthos — "right" — in allusion to its right-angle cleavage. Haüy meant the name to designate a kind of feldspar but did not specify a type-locality, nor publish a chemical analysis. The label was provisional.

Two decades later the German mineralogist Johann Friedrich August Breithaupt rebuilt it. In 1823 he renamed the species orthoklas, from the same orthos plus klasis — "cleaving". The geometric reference was now explicit. The modern form orthoclase descends from Breithaupt's coinage.

Nineteenth- and twentieth-century work clarified what orthoclase actually is among the potassium feldspars. The species shares the formula K(AlSi₃O₈) with two siblings. Sanidine is the high-temperature form, with aluminium and silicon atoms randomly distributed across the available sites in the crystal framework. Microcline is the low-temperature form, with the same atoms fully ordered into fixed positions. Orthoclase sits between the two — the intermediate-temperature case, with atoms partially ordered rather than randomly arranged.

Industrial & practical applications

Orthoclase is one of the workhorse minerals of the ceramics trade. Crushed with the other potassium feldspars, it goes into porcelain, sanitaryware, wall tile, and tableware bodies as a flux. A flux is a fusible component that melts during firing and forms a glassy phase, binding the harder grains around it. Typical additions are 15 to 30 % feldspar in tableware, around 25 % in sanitaryware, and up to 80 % in dental porcelain. The same role carries into ceramic glazes, where feldspar lowers the temperature at which the glaze vitrifies and seals the surface.

Glassmaking takes the bulk of feldspar production. The mineral supplies both alkali (K₂O, Na₂O) and alumina (Al₂O₃) to the melt. The alkali fluxes the batch; the alumina improves hardness, durability, and resistance to chemical corrosion in the finished glass. About 66 % of feldspar consumed in the United States ends up in glassmaking, including glass containers and glass fibre.

Beyond bodies and batches, orthoclase has a third quiet job: as a mild abrasive in household scouring products. Bar Keepers Friend and Bon Ami both use feldspar as their abrasive grit, fine enough to clean a sink without scratching the enamel. Crushed orthoclase also serves as decorative facing in slabbed rock panels and as ordinary crushed stone.

Two varieties move through the gem trade. Adularia is a low-temperature form whose intergrowths with albite scatter light in soft pearly sheets. That sheen, called adularescence, is what makes moonstone a moonstone.

World feldspar production reached an estimated 26 million tonnes in 2020, with Turkey, India, Italy, and China the four largest producers. The published figures aggregate orthoclase with the other potassium and sodium feldspars; orthoclase-specific tonnage is not separately reported.

Where it forms, where it's found

Geological setting

Common feldspar of high-temperature granites, syenites, high-grade metamorphic rocks, and some felsic extrusive rocks, eg some rhyolites (although these tend to contain sanidine when fresh).

2,638recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless to white · greenish white · grayish yellow · pale pink
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect on (001), good on (010)

Fracture
Irregular/Uneven · Conchoidal
Density
2.55 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 35 – 75° · 2V calc = 52 – 70°
Refractive index
1.518 – 1.525
Surface relief
Moderate
Principal indices
nα 1.518 – 1.520 · nβ 1.522 – 1.524 · nγ 1.522 – 1.525
Birefringence
0.004
Pleochroism
Non-pleochroic
Dispersion
r > v distinct
Extinction
X^a = 6°-14°, Y^c = -13° to 21°, Z = b
UV response
May fluoresce dull white or red in SW UV
Michel-Lévy diagramhighlighted lineδ = 0.0040
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]40 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation40 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 8.5632(11) Å · b = 12.963(14) Å · c = 7.299(11) Å
Cell angles
β = 116.073(9) °
Ratio a:b:c
1 : 1.514 : 0.852
Unit cell volume
724.57 ų
Z
4
Morphology

Short prismatic

Twinning

Common as Carlsbad, Baveno and Manebach.

Parting
On (100) (110) (110) (201)
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
45.99%
14SiSiliconSilicon328.08584.255
30.27%
19KPotassiumPotassium139.09839.098
14.05%
13AlAluminiumAluminium126.98226.982
9.69%
Total278.327100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Na
  • Fe
  • Ba
  • Rb
  • Ca

Synonyms

  • Aglairit
  • Argillyit
  • Argillyita
  • Argillyite
  • Common Feldspar
  • Cottait
  • Cottaita
  • Cottaite
  • Leelit
  • Leelita
  • Leelite
  • Muldan
  • Murchisonit
  • Murchisonita
  • Murchisonite
  • Ortose
  • Paradoxit

In other languages

French
Orthose
German
Orthoklas
Spanish
ortoclasa
Italian
ortoclasio
Portuguese
ortoclase
Japanese
正長石
Chinese
正長石
Russian
ортоклаз
Arabic
أرثوكلاز · أرثوكليز · أورثوكلاز · أورثوكلاس · أورثوكليس

Classification

Strunz
10th ed.

9.FA.30

  • 9SilicatesClass
  • 9.FTektosilicates without zeolitic H2ODivision
  • 9.FATektosilicates without additional non-tetrahedral anionsGroup
  • 9.FA.30OrthoclaseSpecies
Dana
8th ed.

76.01.01.01

  • 76Tectosilicates Al-si FrameworkClass
  • 76.01Al-Si Framework with Al-Si frameworksType
  • 76.01.01K (Na,Ba) feldsparsGroup
  • 76.01.01.01OrthoclaseSpecies
CIM

16.3.6

  • 16Silicates Containing Aluminum and other MetalsClass
  • 16.3Aluminosilicates of KGroup
  • 16.3.6OrthoclaseSpecies

Group, growth & confusion

In the same group
2 members
Commonly confused with
4 minerals

Literature, links & citation

Citations
  1. 1954Coombs, D. S. (1954) Ferriferous orthoclase from Madagascar. Mineralogical Magazine and Journal of the Mineralogical Society, 30 (226) 409-427 doi:10.1180/minmag.1954.030.226.01 DOI: 10.1180/minmag.1954.030.226.01
  2. 1962Brace, W. F., Walsh, J. B. (1962) Some direct measurements of the surface energy of quartz and orthoclase. American Mineralogist, 47 (9-10) 1111-1122
  3. 1968Wright, Thomas L., Stewart, David B. (1968) X-ray and optical study of alkali feldspar: I. Determination of composition and structural state from refined unit-cell parameters and 2V. American Mineralogist, 53 (1-2) 38-87
  4. 1968Wright, Thomas L. (1968) X-ray and optical study of alkali feldspar: II. An X-ray method for determining the composition and structural state from measurement of 2θ values for three reflections. American Mineralogist, 53 (1-2) 88-104
  5. 1973Prince, Edward, Donnay, Gabrielle, Martin, R. F. (1973) Neutron diffraction refinement of an ordered orthoclase structure. American Mineralogist, 58 (5-6). 500-507
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Orthoclase — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/orthoclase-3026},
  note      = {Accessed 2026-05-11}
}