Pseudobrookite

(Fe3+2Ti)O5
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pbrk
Discovered
1878

History

The name is a small confession. Pseudobrookite joins the Greek pseudes — false — to brookite, an admission that the new mineral was a convincing impostor. Brookite is a form of titanium dioxide, and pseudobrookite's crystals looked enough like it to mislead the eye. Look past the surface, though, and the two are different minerals: pseudobrookite is an oxide of both iron and titanium, with the formula Fe₂TiO₅, not titanium alone.

The mineral was first described in 1878. The describing specimens came from Uroi Hill — also called Arany Hill — near Simeria, in Hunedoara County, Romania. That hill is the type locality, the place a mineral is formally tied to when it is named.

Pseudobrookite is a child of volcanic heat. It grows by pneumatolytic deposition — crystallising straight out of hot volcanic gases — and by alteration inside titanium-rich lavas. The host rocks are andesite, rhyolite and basalt. It is a frequent guest in lithophysae, the hollow bubble-like cavities that open in such lavas as trapped gas expands. The Romanian crystals that earned it a name sat in exactly this kind of volcanic setting.

Industrial & practical applications

Pseudobrookite has no recorded industrial use. It is a rare accessory mineral — a minor extra that turns up scattered through a rock rather than forming bodies large enough to mine. It crystallises from volcanic gases inside titanium-rich lavas and in the gas cavities called lithophysae, settings that never concentrate it into a workable ore. Its interest is scientific and aesthetic: it is collected as a representative of its species and studied as one of the iron–titanium oxides that record how a magma cooled. No source documents any present-day commercial application.

Where it forms, where it's found

Geological setting

Magmatic, post-volcanic or young volcanic rocks. Typically formed by pneumatolytic processes in titanium-rich andesite, rhyolite, basalt, etc., and by reactions with xenoliths within these; in lithophysae. Rarely in plutonic rocks.

Type locality
Uroi Hill (Arany Hill)
  1. Simeria
  2. Hunedoara County
  3. Romania

45.8605°, 23.0444°

178recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine - Metallic
Transparency
Transparent · Opaque
Colour
Brownish black · reddish brown · or black
Streak
Reddish brown to ocher-yellow
Cleavage
Distinct/Good

On (010) distinct

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
4.33 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50° · 2V calc = 80°
Refractive index
2.35 – 2.42
Surface relief
Very high
Principal indices
nα 2.35 – 2.38 · nβ 2.36 – 2.39 · nγ 2.38 – 2.42
Pleochroism
Weak

In browns.

Dispersion
none
Extinction
Y = a; Z = c; X ∧ a = 26°.
Tropism
Anisotropic
Reflectance R%
(22.8,24.0) 400, (21.9,23.1) 420, (21.2,22.3) 440, (20.5,21.4) 460, (19.8,20.7) 480, (19.4,20.4) 500, (19.0,19.9) 520, (18.5,19.3) 540, (18.1,18.8) 560, (17.8,18.5) 580, (17.5,18.1) 600, (17.3,17.9) 620, (17.1,17.7) 640, (17.0,17.6) 660, (16.8,17.4) 680, (16.7,17.3) 700
Luminescence
Non-fluorescent
Reflected-light panel
18.8 %anisotropic · dual curve
Specimen sRGB 154, 110, 65
White reference100 % reflector under same lamp
R₁ R₂
Mode

Crystallography

Crystal system
Orthorhombic
Space group
#50
Cell parameters
a = 9.7965(25) Å · b = 9.9805(25) Å · c = 3.7301(1) Å
Ratio a:b:c
1 : 1.019 : 0.381
Z
4
Morphology

Crystals usually tabular (100) and elongated [001]; long prismatic at times or needle-like [001]. (100) and {hk0} striated [001].

Twinning

Reported on various {hk0} planes (doubtful).

Epitaxy

Pseudobrookite on hematite with pseudobrookite (121)[2_10] parallel to hematite (0001)[1_100]. Pseudobrookite on magnetite with pseudobrookite (100)[001] parallel to magnetite (111)[110]. Oriented inclusions of rutile in pseudobrookite.

Comment

Space Group: Bbmm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
26FeIronIron255.845111.690
46.63%
8OOxygenOxygen515.99979.995
33.39%
22TiTitaniumTitanium147.86747.867
19.98%
Total239.552100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

In other languages

French
Pseudobrookite
German
Pseudobrookit
Spanish
Pseudobrookita
Italian
Pseudobrookite
Japanese
擬板チタン石
Chinese
假板钛矿

Classification

Strunz
10th ed.

4.CB.15

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CBWith medium-sized cationsGroup
  • 4.CB.15PseudobrookiteSpecies
Dana
8th ed.

07.07.01.01

  • 07Multiple OxidesClass
  • 07.07AB2X5Type
  • 07.07.01— unnamed intermediate level —Group
  • 07.07.01.01PseudobrookiteSpecies
CIM

7.9.16

  • 7Oxides and HydroxidesClass
  • 7.9Oxides of TiGroup
  • 7.9.16PseudobrookiteSpecies

Group, growth & confusion

In the same group
4 members
Often grow together
13 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Ottemann, J., Frenzel, G. (1965) Der Chemismus der Pseudobrookite von Vulkaniten. Schweizerische Mineralogische und Petrographische Mitteilungen: 45: 819-836 (in German with English abstract).
  2. 1878Koch, A. (1878) XXII. Neue Minerale aus dem Andesit des Aranyer Berges in Siebenbürgen. Tschermaks Mineralogische und Petrographische Mitteilungen 1, Neue Folge: 331-361.
  3. 1878Koch, A. (1878) Neue Minerale. Pseudobrookite und Szabóit. Mineralogische und Petrographische Mittheilungen: 1: 77-79.
  4. 1892Traube, Η. (1892) Ueber den Pseudobrookit vom Aranyer Berge in Siebenbürgen. Zeitschrift für Krystallographie, 20 (1). 327 doi:10.1524/zkri.1892.20.1.327DOI: 10.1524/zkri.1892.20.1.327
  5. 1930Pauling, Linus (1930) The crystal structure of pseudobrookite. Zeitschrift für Kristallographie, 73 (1). 97-112 doi:10.1524/zkri.1930.73.1.97DOI: 10.1524/zkri.1930.73.1.97
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pseudobrookite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pseudobrookite-3302},
  note      = {Accessed 2026-05-11}
}