Hydroxylherderite

CaBe(PO4)(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hhd
Discovered
1894
Also known as
  • Hydro-fluorherderite
  • Hydro-herderite
  • Hydroxylherderiet
  • +1 more

Where it forms, where it's found

Geological setting

granite pegmatite

Late stage mineral in miarolitic cavities in complex granitic pegmatites, alteration of beryl or beryllonite, hydrothermal.

111recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colorless · gray · brown · pale yellow · greenish white · light blue · purple · colourless in transmitted light.

May be blue-green or blue in daylight, lavender or light violet in incandescent light

Streak
white
Tenacity
brittle
Cleavage
Poor/Indistinct

On (110), interrupted.

Fracture
Irregular/Uneven
Density
2.95 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70 – 77° · 2V calc = 64°
Refractive index
1.589 – 1.643
Surface relief
Moderate
Principal indices
nα 1.589 – 1.615 · nβ 1.610 – 1.634 · nγ 1.619 – 1.643
Birefringence
0.029
Pleochroism
Non-pleochroic
Dispersion
r > v inclined
Extinction
inclined
UV response
Weak yellow under SW Sometimes bright yellow-orange phosphorescence
Michel-Lévy diagramhighlighted lineδ = 0.0290
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]290 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation290 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 9.789(2) Å · b = 7.661(1) Å · c = 4.804(1) Å
Cell angles
β = 90.02 °
Ratio a:b:c
1 : 0.783 : 0.491
Z
4
Morphology

Stout prismatic crystals [100] or [001]; thick tabular (001). Commonly pseudo-orthorhombic in aspect, rarely monoclinic; pseudo-hexagonal [001] at times. Also occurs as botryoidal or spheroidal aggregates with a radial-fibrous structure.

Twinning

On (100) or (001) as fishtail contact. Most crystals are twinned; however, some exhibit no outward signs of this morphology.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
49.67%
20CaCalciumCalcium140.07840.078
24.88%
15PPhosphorusPhosphorus130.97430.974
19.23%
4BeBerylliumBeryllium19.0129.012
5.59%
1HHydrogenHydrogen11.0081.008
0.63%
Total161.067100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hydro-fluorherderite
  • Hydro-herderite
  • Hydroxylherderiet
  • Hydroxylherderita

In other languages

German
Hydroxylherderit
Italian
Hydroxylherderite · Idrossilherderite

Classification

Strunz
10th ed.

8.BA.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BAWith small and medium-sized cationsGroup
  • 8.BA.10HydroxylherderiteSpecies
Dana
8th ed.

41.05.04.02

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.05(AB)2(XO4)ZqType
  • 41.05.04Herderite GroupGroup
  • 41.05.04.02HydroxylherderiteSpecies
CIM

19.3.4

  • 19PhosphatesClass
  • 19.3Phosphates of Be and MgGroup
  • 19.3.4HydroxylherderiteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1884Dana, E.S. (1884) On the crystalline form of the supposed herderite from Stoneham, Maine. American Journal of Science: 27: 229-232.
  2. 1884Des Cloizeaux, A. (1884) Sur l'identité optique des cristaux de Herdérite d'Ehrenfriedersdorf (en Saxe) et de Stoneham (Etat du Maine). Bulletin de la Société française de Minéralogie: 7: 130.
  3. 1886Bertrand in: Des Cloizeaux (1886) Bulletin de la Société française de Minéralogie: 9: 141.
  4. 1886Penfield, S.L., Harper, D.N. (1886) On the chemical composition of herderite and beryl, with note on the precipitation of aluminum and separation of beryllium and aluminum. American Journal of Science: s3-32(188): 107-117.
  5. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hydroxylherderite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hydroxylherderite-1962},
  note      = {Accessed 2026-05-11}
}