Magnesite

Mg(CO3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mgs
Discovered
1808
Also known as
  • Baldissérit
  • Baldissérita
  • Baldissérite
  • +27 more

History

The name magnesite traces back to a single corner of the map. It comes from Magnesia, a district in Thessaly, in Greece, where the pale magnesium-rich minerals first lent their region's name to the substance.

That place name spread further than almost any other in chemistry. The ancient Greeks called the lodestone — a naturally magnetic rock — the Magnesian stone, and from it we get the word magnet. By a separate twist of the same root, the ore that became manganese carried the name too. Magnesite, the carbonate of magnesium, belongs to the same crowded family of words.

The mineral was formally pinned to its type locality, Magnesia, in 1808. That was the same year the British chemist Humphry Davy first isolated the metal magnesium. He drew it from a white powder once sold in Rome as magnesia alba.

Industrial & practical applications

Most magnesite never reaches a buyer as magnesite. It is roasted first. Heating the mineral drives off carbon dioxide and leaves behind magnesium oxide, a white solid also called magnesia. Magnesia resists heat better than almost anything cheap. That single transformation is what makes magnesite a commodity rather than a curiosity.

In industry

The roasting can be gentle or fierce, and the temperature decides the product. A light burnt roast, starting around 450 °C and stopping below 900 °C, leaves the magnesia reactive and chemically eager. Push past 900 °C and the crystal structure collapses into a dense, chemically inert form called dead-burnt magnesia.
Dead-burnt magnesia is the workhorse. It is shaped into refractory products — heat-resistant linings — for the furnaces that make iron and steel, nonferrous metals, glass, and cement. These furnaces run hot enough to melt most materials; a magnesia lining is one of the few things that holds.

The light, reactive grade goes almost everywhere else. Sold as caustic-calcined magnesia, it feeds environmental, chemical, and agricultural uses, along with road deicing. In the United States these reactive compounds — caustic-calcined magnesia plus magnesium chloride, hydroxide, and sulfates — take about 78 percent of demand. The refractory grades are the smaller share.

Magnesite also supplies the wider world of magnesium chemistry. It serves as a starting material for magnesium chemicals and fertilizers, and as a catalyst and filler in making synthetic rubber. Ground and bound with a setting agent, it forms the hard surface of magnesite-screed flooring. Cut and polished, the raw mineral even turns up as beads in costume jewelry.

Supply and outlook

World magnesite mining runs to roughly 22 million tons a year, measured by gross weight. One country dominates: China alone accounts for about 13 of those million tons. Identified world resources of magnesite and brucite together reach some 13 billion tons, so scarcity is not the constraint — processing capacity and geography are. Where magnesia is too costly, alumina, chromite, and silica can stand in for it in some refractory linings.

Where it forms, where it's found

Geological setting

Primary mineral in igneous and sedimentary rocks. Rarely as a gangue mineral in hydrothermal ore veins, and in oceanic salt deposits. Metamorphism of serpentinites and peridotites.

Type locality
Magnesia
  1. Thessaly
  2. Greece
1,583recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789103.5 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Colourless · white · greyish-white · yellowish · brown · faintly pink · lilac-rose · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (1011).

Fracture
Conchoidal
Density
2.98 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.509 – 1.7
Surface relief
Moderate
Principal indices
nω 1.7 · nε 1.509
Pleochroism
Visible

Cobaltian material dichroic: E = Violet-red O = Flesh-red

Dispersion
Very strong
UV response
May exhibit pale green to pale blue fluorescence and phosphorescence.
Michel-Lévy diagramhighlighted lineδ = 0.1910
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1910 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1910 nm
Order4th order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#98
Cell parameters
a = 4.6632 Å · c = 15.015 Å
Z
6
Morphology

Crystals usually rhombohedral (1011), also (0112); prismatic rare [0001] with (1120) and (0001), or tabular (0001). Scalenohedral rare. Massive, coarse- to fine-granular, very compact and porcelainous; earthy to rather chalky; lamellar; coarsely fibrous.

Twinning

Unproven.

Comment

Cell parameters are similar to those of smithsonite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen315.99947.997
56.93%
12MgMagnesiumMagnesium124.30524.305
28.83%
6CCarbonCarbon112.01112.011
14.24%
Total84.313100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Mn
  • Ca
  • Co
  • Ni
  • ORG

Synonyms

  • Baldissérit
  • Baldissérita
  • Baldissérite
  • Bandisserit
  • Bandisserita
  • Bandisserite
  • Baudisserit
  • Baudisserita
  • Baudisserite
  • Bitterspat
  • Carbonate of Magnesia
  • Giobertit
  • Giobertita
  • Giobertite
  • Kohlensaure Bittererde
  • Kohlensaurer Talkerde
  • Magnesianit
  • Magnesianita
  • Magnesianite
  • Magnésie carbonatée
  • Magnesite (of Karsten)
  • Magnesiumcarbonat
  • Mesitit
  • Mesitita
  • Reine Talkerde
  • Roubschit
  • Roubschita
  • Roubschite
  • Talcum carbonatum
  • Talkspat

In other languages

French
13717-00-5 · Baldissérite · Breinnerite · E504 · E504(i) · Ferroan magnesite · Hallite · Hoshiite · Magnésianite · magnésite · Magnésium carbonate de · Mésitine · Mesitite · Nickel-magnésite
German
Breunnerit · Magnesit · Mesitinspat · Pinolenstein · Pinolitmagnesit
Spanish
giobertita · magnesita
Italian
magnesite
Portuguese
magnesita · Magnesite
Japanese
マグネサイト · 菱苦土石 · 菱苦土鉱
Chinese
菱鎂礦
Simplified Chinese
菱镁矿
Traditional Chinese
菱鎂礦
Russian
Магнезит
Arabic
مغنيسيت
Hindi
मैग्नेसाइट

Classification

Strunz
10th ed.

5.AB.05

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.ABAlkali-earth (and other M2+) carbonatesGroup
  • 5.AB.05MagnesiteSpecies
Dana
8th ed.

14.01.01.02

  • 14Anhydrous Normal CarbonatesClass
  • 14.01A(XO3)Type
  • 14.01.01Calcite Group (Trigonal: R-3c)Group
  • 14.01.01.02MagnesiteSpecies
CIM

11.3.1

  • 11CarbonatesClass
  • 11.3Carbonates of MgGroup
  • 11.3.1MagnesiteSpecies

Group, growth & confusion

In the same group
7 members

Literature, links & citation

Citations
  1. 1795Klaproth, M. H. (1795) XXI. Untersuchung des Bitterspath. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 1. Rottmann. p.300-306.
  2. 1800Mitchell and Lampadius (1800) 3: 241 (as Kohlensaure Talkerde).
  3. 1803Werner: Ludwig, C.F. (1803-1804) Handbuch der Mineralogie nach A.G. Werner. 2 volumes, Leipzig: 2: 154 (as Reine Talkerde, Talcum carbonatum).
  4. 1810Klaproth, M. H. (1810) CLXXXV. Untersuchung des Magnesits aus Steiermark. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 5. Rottmann. p.97-104.
  5. 1873Koksharov, Nikolai (1873) Materialien zur Mineralogie Russlands Vol. 7. Carl Kray.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Magnesite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/magnesite-2482},
  note      = {Accessed 2026-05-11}
}